In this paper, the influences of specimen size and test temperature on the viscoelastic properties of SU-8 photoresist films are described. Films with the thicknesses of 1 μm and 10 μm are subjected to quasi-static uniaxial tensile tests and stress relaxation tests at temperatures ranging from 293 K to 473 K. The average glassy modulus at 293 K is 3.2 GPa, which decreases with an increase in the test temperature irrespective of specimen size. The mean fracture strain depends on film thickness as well as temperature. The fracture strain of the 1-μm thick films is approximately half of that of the 10-μm thick films at each temperature. Stress relaxation tests are conducted for constructing the master curves of the relaxation moduli. There is no apparent thickness dependence on the master curve. Above glass transition temperature, Tg, apparent activation energies for the two films are almost identical, whereas the activation energy for the thinner films is smaller than that for the thicker films below Tg. This size effect is discussed using Fourier transform infrared spectroscopy (FTIR).

References

1.
Lorenzyz
,
H.
,
Despontxk
,
M.
,
Fahrniy
,
N.
,
LaBianca
,
N.
,
Renaudy
,
P.
, and
Vettigerx
,
P.
,
1997
, “
SU-8: A Low-Cost Negative Resist for MEMS
,”
J. Micromech. Microeng.
,
7
(
3
), pp.
121
124
.
2.
Fujita
,
T.
,
Maenaka
,
K.
, and
Takayama
,
Y.
,
2005
, “
Dual-Axis MEMS Mirror for Large Deflection-Angle Using SU-8 Soft Torsion Beam
,”
Sens. Actuators, A
,
121
(
1
), pp.
16
21
.
3.
Delille
,
R.
,
Urdaneta
,
M. G.
,
Moseley
,
S. J.
, and
Smela
,
E.
,
2006
, “
Benchtop Polymer MEMS
,”
J. Microelectromech. Syst.
,
15
(
5
), pp.
1108
1120
.
4.
Miura
,
T.
,
Suzuki
,
T.
,
Terao
,
K.
,
Takao
,
H.
,
Oohira
,
F.
,
Kaibara
,
Y.
, and
Namazu
,
T.
,
2011
, “
Fabrication and Evaluation of Polymer MEMS Mirror Based on the Mechanical Characteristic of Polymer Containing Magnetic Particles
,”
16th International Conference on Optical MEMS & Nanophotonics
(
OMN2011
), Istanbul, Aug. 8–11, pp.
175
176
.
5.
Nakahara
,
T.
,
Hosokawa
,
Y.
,
Terao
,
K.
,
Takao
,
H.
,
Shimokawa
,
F.
,
Oohira
,
F.
,
Namazu
,
T.
,
Kotera
,
H.
, and
Suzuki
,
T.
,
2012
, “
A Magnetic-Driven Membrane Made of Photosensitive Nanocomposite Without Alignment Process
,”
7th IEEE International Conference on Nano/Micro Engineered and Molecular Systems (IEEE-NEMS)
, pp.
233
234
.
6.
Nordström
,
M.
,
Keller
,
S.
,
Lillemose
,
M.
,
Johansson
,
A.
,
Dohn
,
S.
,
Haefliger
,
D.
,
Blagoi
,
G.
,
Havsteen-Jakobsen
,
M.
, and
Boisen
,
A.
,
2008
, “
SU-8 Cantilevers for Bio/Chemical Sensing; Fabrication, Characterisation and Development of Novel Read-Out Methods
,”
Sensors
,
8
(
3
), pp.
1595
1612
.
7.
Allena
,
N.-J.
,
Wood
,
D.
,
Rosamond
,
M.-C.
, and
Sims-Williams
,
D.-B.
,
2009
, “
Fabrication of an In-Plane SU-8 Cantilever With Integrated Strain Gauge for Wall Shear Stress Measurements in Fluid Flows
,”
Procedia Chem.
,
1
(
1
), pp.
923
926
.
8.
Johansson
,
A.
,
Calleja
,
M.
,
Rasmussen
,
P. A.
, and
Boisen
,
A.
,
2005
, “
SU-8 Cantilever Sensor System With Integrated Readout
,”
Sens. Actuators, A
,
123–124
, pp.
111
115
.
9.
Brennan
,
D.
,
Lambkin
,
P.
,
Moore
,
E. J.
, and
Galvin
,
P.
,
2008
, “
An Integrated Optofluidic Platform for DNA Hybridization and Detection
,”
IEEE Sens. J.
,
8
(
5
), pp.
536
542
.
10.
Jiang
,
Z.
,
Llandro
,
J.
,
Mitrelias
,
T.
, and
Bland
,
J. A. C.
,
2006
, “
An Integrated Microfluidic Cell for Detection, Manipulation, and Sorting of Single Micron-Sized Magnetic Beads
,”
J. Appl. Phys.
,
99
(
8
), p.
08S105
.
11.
Ruano
,
J. M.
,
Aguirregabiria
,
M.
,
Tijero
,
M.
,
Arroyo
,
M.
,
Garcia
,
J.
,
Berganzo
,
J.
,
Aramburu
,
I.
,
Blanco
,
F. J.
, and
Mayora
,
K.
,
2004
, “
Monolithic Integration of Microfluidic Channels and Optical Waveguides Using a Photodefinable Epoxy
,”
17th IEEE International Conference on Microelectromechanical Systems
(
MEMS
), Maastricht, The Netherlands, Jan. 25–29, pp.
121
124
.
12.
Lin
,
C.-H.
,
Lee
,
G.-B.
,
Chang
,
B.-W.
, and
Chang
,
G.-L.
,
2002
, “
A New Fabrication Process for Ultra-Thick Microfluidic Microstructures Utilizing SU-8 Photoresist
,”
J. Micromech. Microeng.
,
12
(
5
), pp.
590
597
.
13.
Carlier
,
J.
,
Arscott
,
S.
,
Thomy
,
V.
,
Fourrier
,
J. C.
,
Caron
,
F.
,
Camart
,
J. C.
,
Druon
,
C.
, and
Tabourier
,
P.
,
2004
, “
Integrated Microfluidics Based on Multi-Layered SU-8 for Mass Spectrometry Analysis
,”
J. Micromech. Microeng.
,
14
(
4
), pp.
619
624
.
14.
Inoue
,
M.
,
Okonogi
,
A.
,
Terao
,
K.
,
Takao
,
H.
,
Shimokawa
,
F.
,
Oohira
,
F.
,
Kotera
,
H.
, and
Suzuki
,
T.
,
2012
, “
Cell Culture on MEMS Materials in Microenvironment Limited by a Physical Condition
,”
Micro Nano Lett.
,
7
(
8
), pp.
725
728
.
15.
Suzuki
,
T.
,
Terao
,
K.
,
Suzuki
,
H.
,
Nitta
,
Y.
,
Takao
,
H.
,
Shimokawa
,
F.
,
Oohira
,
F.
,
Hiramaru
,
D.
, and
Kotera
,
H.
,
2012
, “
DNA Fiber Preparation Technique on a Chip for Clinical Diagnosis
,”
16th International Conference on Miniaturized Systems for Chemistry and Life Sciences
, Okinawa, Japan, Oct. 28–Nov. 1, pp.
272
274
.
16.
Morikaku
,
T.
,
Kaibara
,
Y.
,
Inoue
,
M.
,
Miura
,
T.
,
Suzuki
,
T.
,
Oohira
,
F.
,
Inoue
,
S.
, and
Namazu
,
T.
,
2013
, “
Influences of Pretreatment and Hard Baking on Mechanical Reliability of SU-8 Microstructures
,”
J. Micromech. Microeng.
,
23
(
10
), p.
105016
.
17.
Feng
,
R.
, and
Farris
,
R. J.
,
2002
, “
The Characterization of Thermal and Elastic Constants for an Epoxy Photoresist SU8 Coating
,”
J. Mater. Sci.
,
37
(
22
), pp.
4793
4799
.
18.
Ishiyama
,
C.
,
Shibata
,
A.
,
Sone
,
M.
, and
Higo
,
Y.
,
2010
, “
Effects of Aspect Ratio of Photoresist Patterns on Adhesive Strength Between Microsized SU-8 Columns and Silicon Substrate Under Bend Loading Condition
,”
Jpn. J. Appl. Phys., Part 1
,
49
(
6
), p.
06GN14
.
19.
Ishiyama
,
C.
,
Sone
,
M.
, and
Higo
,
Y.
,
2007
, “
Effects of Heat Curing on Adhesive Strength Between Microsized SU-8 and Si Substrate
,”
Proc. SPIE
,
6533
, p.
65331F
.
20.
Kisara
,
M.
, and
Ducree
,
J.
,
2013
, “
Integration of Functional Materials and Surface Modification for Polymeric Microfluidic Systems
,”
J. Micromech. Microeng.
,
23
(
3
), p.
033001
.
21.
Namazu
,
T.
,
Nagai
,
Y.
,
Naka
,
N.
,
Araki
,
N.
, and
Inoue
,
S.
,
2011
, “
Design and Development of a Biaxial Tensile Test Device for a Thin Film Specimen
,”
ASME J. Eng. Mater. Technol.
,
134
(
1
), p.
011009
.
22.
Fujii
,
M.
,
Namazu
,
T.
,
Fujii
,
H.
,
Masunishi
,
K.
,
Tomizawa
,
Y.
, and
Inoue
,
S.
,
2012
, “
Quasi-Static and Dynamic Mechanical Properties of Al-Si-Cu Structural Films in Uniaxial Tension
,”
J. Vac. Sci. Technol., B
,
30
(
3
), p.
031804
.
23.
Namazu
,
T.
,
Fujii
,
M.
,
Fujii
,
H.
,
Masunishi
,
K.
,
Tomizawa
,
Y.
, and
Inoue
,
S.
,
2013
, “
Thermal Annealing Effect on Elastic-Plastic Behavior of Al-Si-Cu Structural Films Under Uniaxial and Biaxial Tension
,”
J. Microelectromech. Syst.
,
22
(
6
), pp.
1414
1427
.
24.
Gaspar
,
J.
,
Schmidt
,
M. E.
,
Held
,
J.
, and
Paul
,
O.
,
2009
, “
Wafer-Scale Microtensile Testing of Thin Films
,”
J. Microelectromech. Syst.
,
18
(
5
), pp.
1062
1076
.
25.
Namazu
,
T.
,
Inoue
,
S.
,
Takemoto
,
H.
, and
Koterazawa
,
K.
,
2005
, “
Mechanical Properties of Polycrystalline Titanium Nitride Films Measured by XRD Tensile Testing
,”
IEEJ Trans. Sens. Micromach.
,
125
(
9
), pp.
374
379
.
26.
Namazu
,
T.
, and
Inoue
,
S.
,
2007
, “
Characterization of Single Crystal Silicon and Electroplated Nickel Films by Uniaxial Tensile Test With In Situ X-Ray Diffraction Measurement
,”
Fatigue Fract. Eng. Mater. Struct.
,
30
(
1
), pp.
13
20
.
27.
Namazu
,
T.
,
Takemoto
,
H.
,
Fujita
,
H.
, and
Inoue
,
S.
,
2007
, “
Uniaxial Tensile and Shear Deformation Tests of Gold-Tin Eutectic Solder Film
,”
J. Sci. Technol. Adv. Mater.
,
8
(
3
), pp.
146
152
.
28.
Namazu
,
T.
,
Hashizume
,
A.
, and
Inoue
,
S.
,
2007
, “
Thermomechanical Tensile Characterization of Ti-Ni Shape Memory Alloy Films for Design of MEMS Actuator
,”
Sens. Actuators, A
,
139
(
1
), pp.
178
186
.
29.
Namazu
,
T.
, and
Isono
,
Y.
,
2009
, “
Fatigue Life Prediction Criterion for Micro-Nanoscale Single-Crystal Silicon Structures
,”
J. Microelectromech. Syst.
,
18
(
1
), pp.
129
137
.
30.
Namazu
,
T.
,
Takemoto
,
H.
, and
Inoue
,
S.
,
2010
, “
Tensile and Creep Characteristics of Sputtered Gold-Tin Eutectic Solder Film Evaluated by XRD Tensile Testing
,”
Sens. Mater.
,
22
(
1
), pp.
13
24
.
You do not currently have access to this content.